12-83 For a homogeneous (single-phas e) simple pure substance, the pressure and temperature are independent properties, and any property can be expressed as a function of these two properties. Taking v = v(P, T), show that the change in specific volume can be expressed in terms of the volume expansivity b and isothermal compressibility a as Also, assuming constant average values for b and a, obtain a relation for the ratio of the specific volumes v2/v1 as a homogeneous system undergoes a process from state 1 to state 2. | |
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